Oxidative addition of ether O-methyl bonds at a Pt(0) centre.
نویسندگان
چکیده
Pt(PCyp3)2 (Cyp = cyclopentyl) undergoes C-O oxidative addition with 2,3,5,6-tetrafluoro-4-methoxypyridine, pentafluoroanisole, 2,3,5,6-tetrafluoroanisole and 2,3,6-trifluoroanisole yielding platinum methyl derivatives. The reactions occur in preference to C-H or C-F activation.
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عنوان ژورنال:
- Chemical communications
دوره 50 30 شماره
صفحات -
تاریخ انتشار 2014